Objective: To explore the mediating effect of coping style on perfectionism and employment anxiety among undergraduate students, and to provide evidence for eliminating their employment anxiety. Methods: Totally 220 undergraduate students were selected and asked to complete the Frost multidimensional perfectionism scale, coping style questionnaire and employment anxiety questionnaire. Results: The results show the following: (1) the female undergraduate students show more employment uneasy than the male students, and the medical students show more job anxiety than the non-medical students. (2) There are significantly positive correlations among maladaptive perfectionism, negative coping style and employment anxiety. (3) Negative coping style partially mediates the relationship between maladaptive perfectionism and employment anxiety. Maladaptive perfectionism and negative coping style play important roles in undergraduate students’ employment anxiety. Conclusion: We should avoid the negativeSinfluences of the maladaptive perfectionism and reduce the frequency of negative coping style to ease the employment anxiety of undergraduates.